Selecting the most
appropriate O2 analyzer to use depends on a number of factors such as
environmental conditions and desired accuracy. Some instruments are able to
measure very small traces of oxygen while others are most suitable for larger
concentrations. The principle of operation for different analyzers also varies.
The most common types of instruments used to measure O2 concentration are
Zirconia analyzers and paramagnetic analyzers. Their names can evidently tell
the principle used to measure oxygen. Each one of them has its strengths and
weaknesses as well. A brief study of their operation might help in making a
suitable selection.
The paramagnetic O2 analyzer works on the principle that the effect of magnetism on oxygen
molecules is larger than in other gases. Therefore, other gases are neglected
during analysis. The main chamber consists of two spherical glasses with
different magnetic susceptibility. Oxygen molecules are passed between the
balls and are attracted towards the sphere with a stronger magnetic field. This
leads to a deviation that is recorded by a light sensor. The extent of
deviation is used to determine the concentration of oxygen gas. A special
advantage of this method is that no heat is used or produced during the
process.
The zirconia O2
analyzer on the other hand makes use of a zirconia ceramic unit. The
conductivity of this material is used to determine the concentration of oxygen
gas. In this method, the sample gas and reference gas are placed on either
sides of the ceramic wall. The wall allows for oxygen molecules to pass through
under high temperature. Oxygen ions move from the region of high concentration
to low concentration. This movement generates an EMF that is measured to define
the oxygen content of the sample. This method is very accurate for measuring
low concentrations as well as high concentrations of oxygen.
The best O2 analyzer
to use will depend on a number of factors. The first consideration is whether
there are other flammable gases in the sample. Since the paramagnetic analyzer does
not generate any heat, it is most suitable for measuring flammable samples.
Otherwise, the zirconia type is best suit for very accurate results. Various
precautions should be taken when using these instruments. The manufacturers
usually include precautions in their user manuals. They state the best
conditions under which the instrument can be used and cases that may lead to
damage of various components. All these factors should be considered when using
the O2 detectors.
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