Selective catalytic
reduction of NOx is widely applied in industries that use fossil fuels for
power production. The system is also applied in industrial boilers, utility
boilers and waste boilers where production of NOx is very high. NOx gases are
known for their adverse effects on human and plant life. They are part of the
green gases that have led to global warming and changed weather patterns. Gases
such as nitrogen dioxide are known for their foul smell and negative effect on
visibility. Catalytic reduction systems are meant to reduce these gases by at
least 75% hence ensure environmental conservation and sustainability.
When talking of
Selective catalytic reduction of NOx, two main gases are involved. These are
NOx gases and ammonia. Ammonia is used as a catalyst hence it is not exhausted
during the process. There are two main reactions that occur during the process.
The first reaction occurs between ammonia and nitrogen oxide while the second
reaction occurs between ammonia and nitrogen dioxide. In other cases, the
emissions may also have a considerable amount of oxygen gas. In such a case,
the gas is involved in the reaction to form H2O and nitrogen gas. The other
primary reactions also result in formation of H2O and N2 gas.
Selective catalytic
reduction of NOx was initially common in boilers used in industries. However,
this technology is recently used in diesel engines for selective reduction of
NOx gases. There are a couple of challenges that have been experienced in
diesel engines since they operate on high temperatures. The fact that they
produce particulate matter makes the situation even worse since clogging of
reaction sites is bound to happen. However, some improvements such as use of
strong catalytic ceramics and particulate filtering systems have been made. The
systems ensure that all the emissions are filtered before they are directed to
the catalytic chamber for reduction.
During the selective
catalytic reduction of NOx in boilers and diesel engines, some undesired
reactions between ammonia and other gases may occur. Such cases include the
reaction of ammonia, NO2 and water which leads to the production of ammonium
nitrate. Other cases include the reaction of ammonia with H2SO4 produced from
the reaction between SO3 and water. Such reactions may pose a negative impact
on the catalyst hence making the systems less efficient. However, technologists
are coming up with various improvements such as temperature control systems to ensure
that such occurrences are reduced. This makes selective catalytic of NOx one of
the best methods for reducing NOx emissions.
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